A new issue of this journal has just been published. To see abstracts of the papers it contains (with links through to the full papers) click here:
Selected papers from the latest issue:Lasers Used in Analytical Micropyrolysis
Publication year: 2011
Source: Journal of Analytical and Applied Pyrolysis, In Press, Accepted Manuscript, Available online 11 August 2011
P.F., Greenwood
Laser micropyrolysis gas chromatography mass spectrometry (GCMS) allows analytical pyrolysis to be conducted with micro-spatial resolution. Despite the large range of contemporary laser sources, most previous laser pyrolysis studies have been conducted with continuous wave (CW) infrared irradiation. Here, the laser micropyrolysis analysis of a Sydney torbanite was conducted with three different laser sources–1. CW 532nm; 2. Q-Switched (QSw) pulsed 1064nm; and 3. Q-Sw pulsed 266nm - to compare the molecular analyses attributes of different laser types (λ: 266–1064nm; CW or QSw). The CW 532nm laser irradiation consistently produced high concentrations of n-hydrocarbons, with lesser amounts of cyclic and aromatic...
Source: Journal of Analytical and Applied Pyrolysis, In Press, Accepted Manuscript, Available online 11 August 2011
P.F., Greenwood
Laser micropyrolysis gas chromatography mass spectrometry (GCMS) allows analytical pyrolysis to be conducted with micro-spatial resolution. Despite the large range of contemporary laser sources, most previous laser pyrolysis studies have been conducted with continuous wave (CW) infrared irradiation. Here, the laser micropyrolysis analysis of a Sydney torbanite was conducted with three different laser sources–1. CW 532nm; 2. Q-Switched (QSw) pulsed 1064nm; and 3. Q-Sw pulsed 266nm - to compare the molecular analyses attributes of different laser types (λ: 266–1064nm; CW or QSw). The CW 532nm laser irradiation consistently produced high concentrations of n-hydrocarbons, with lesser amounts of cyclic and aromatic...
Determination of Kinetic Parameters and Analytical Pyrolysis of Tobacco Waste and Sorghum Bagasse
Publication year: 2011
Source: Journal of Analytical and Applied Pyrolysis, In Press, Accepted Manuscript, Available online 4 August 2011
C.R., Cardoso , M.R., Miranda , K.G., Santos , C.H., Ataíde
The thermal decomposition of tobacco waste and sorghum bagasse was investigated by non-isothermal thermogravimetric analyses, applying slow heating rates and well-defined conditions. The purpose of evaluating the decomposition was to estimate the kinetic parameters of the analyzed materials. Activation energies and Arrhenius exponential factors were inferred by different estimation methods: the classical methods of Ozawa and Starink and the independent parallel reactions model. The analytical pyrolysis was performed in a micro-pyrolyzer coupled to a gas chromatographer/mass spectrometer. Values of activation energy obtained with single step reaction models by the Ozawa method were: 103.94kJ/mol for tobacco waste and 120.01kJ/mol for sorghum...
Source: Journal of Analytical and Applied Pyrolysis, In Press, Accepted Manuscript, Available online 4 August 2011
C.R., Cardoso , M.R., Miranda , K.G., Santos , C.H., Ataíde
The thermal decomposition of tobacco waste and sorghum bagasse was investigated by non-isothermal thermogravimetric analyses, applying slow heating rates and well-defined conditions. The purpose of evaluating the decomposition was to estimate the kinetic parameters of the analyzed materials. Activation energies and Arrhenius exponential factors were inferred by different estimation methods: the classical methods of Ozawa and Starink and the independent parallel reactions model. The analytical pyrolysis was performed in a micro-pyrolyzer coupled to a gas chromatographer/mass spectrometer. Values of activation energy obtained with single step reaction models by the Ozawa method were: 103.94kJ/mol for tobacco waste and 120.01kJ/mol for sorghum...
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